This is a lovely piece of work that certainly shows not only that you are evolving into a talented artist, but how you have a good eye and hand in the form of creativity when representing something in a new and different appearance. What you've done is good, the portrayal of this pokemon in a anime/human form has certainly been approached with not only a good understanding of the character personality, but just how to take it and reshape it into something that has energy, charisma and your artistic talents overall.
What's nice about this is how simple you've kept the design, yet shown such a vigorous amount of character animation in her body language and expression on her face as well. It feels animated and really shows that you know how to make a character come to life and be something we can interact with in some regards.
Wow someone knows their war around a Pokemon an damn gotta wonder who much more sexyness we'll have in store when she evolves.
From your Charmander piece can see alot more of a matured tone with her look, and that of course with the skin. A nice shade of red but even more impressive is how well you make it stand out with the some shine and some light shading, well done.
Even the attention to the soft blue eyes really gets your attention and love the added effects of her hair over the other eye, especially how you still managed to add that familiar horn too BDXxX, bravo.
Nicely done work and by the way excellent work with the background and the second image, keep up them sexy Pokemon!